Antioxidant activity and profiles of common vegetables in Singapore

Sixty-six types of vegetables commonly consumed in Singapore were analysed for their hydrophilic oxygen radical absorbance capacity (H-ORAC), total phenolic content (TPC), ascorbic acid (AA) and various lipophilic antioxidants. A single batch analysis of each vegetable showed that antioxidant composition and concentration varied widely across different vegetables. The vegetables with intense colours typically have high H-ORAC, TPC, AA, and carotenoid contents. Vegetables unique to the Asian market such as matrimony vine (Lycium chinense Miller), coriander, Chinese kale, water spinach and red chilli were consistently ranked high in H-ORAC, TPC, carotenoids and vitamin E levels. Based on consumption data, Chinese Singaporeans appear to have a higher intake of lutein, zeaxanthin, β-carotene, and tocopherols compared to the US population. Overall findings suggest that dark green leafy and brightly-coloured vegetables tend to contain high antioxidants. Our data are useful reference and substantiate many public health agencies’ recommendation to consume more vegetables, particularly the dark green leafy and brightly-coloured varieties.     

A review of Znln2S4-based photocatalysts for producing hydrogen by water splitting under visible light: Fundamentals and recent advancements

Hydrogen (H₂) is a clean energy carrier widely used in oil refineries, fertilizers, chemicals, and steel manufacturing. Presently, the majority of H₂ is produced from either steam methane reforming of natural gas or coal gasification; however, these technologies result in a massive amount of CO₂ emission. Alternatively, the use of photocatalysts for producing H₂ via water splitting is an eco-friendly and sustainable approach, among which the selection of highly efficient, stable, and cheap photocatalysts is the key. In this review, Znln₂S₄-based photocatalysts are thoroughly described in terms of the fundamentals and thermodynamics of water splitting, fabrication methods, and different heterostructure photocatalytic systems. After this, recent developments in the large-scale implementation of photocatalytic reactors are discussed. Finally, a summary of future research directions and major conclusions is provided. With proper modification, such as heterojunction systems and the selection of proper fabrication methods, Znln₂S₄-based photocatalysts could be superior materials for water splitting. In short, this review article could offer meaningful and useful insights and guidance for the development of Znln₂S₄-based photocatalysts in water splitting for producing H₂ under visible light.     

Basic Oxygen Furnace: Assessment of Recent Physicochemical Models

Metallurgical and Materials Transactions B - Modeling of the basic oxygen furnace (BOF) process, both for online monitoring and fundamental research, has gained importance in steelmaking industry...     

Highly birefringent large negative dispersion-flattened photonic crystal fibre for broadband residual dispersion compensation

A triangular lattice photonic crystal fibre is presented in this paper for residual dispersion compensation. The fibre exhibits a flattened negative dispersion of ?992.01 ± 6.93 ps/(nm-km) over S+C+L wavelength bands and ?995.83 ± 0.42 ps/(nm-km) over C-band. The birefringence is about 4.4 × 10^?2 at the excitation wavelength of 1550 nm which is also very high. Full vector finite element method (FEM) with a perfectly matched absorbing layer (PML) boundary condition is applied to numerically investigate the guiding properties of this PCF. The fibre operates at fundamental mode only. All these properties endorse this fibre as a suitable candidate for compensating residual dispersion and polarization maintaining applications.     

Dietary exposure of the Belgian population to emulsifiers E481 (sodium stearoyl-2-lactylate) and E482 (calcium stearoyl-2-lactylate)

A dietary exposure assessment of food emulsifiers E481 (sodium stearoyl-2-lactylate) and E482 (calcium stearoyl-2-lactylate) in the Belgian population was performed. Nationally representative food consumption data from the Belgian National Food Consumption Surveys 2004 (BNFCS2004) and 2014 (BNFCS2014) were used for calculations. A conservative approach (combining individual food consumption data with the maximum permitted level (MPL) of foods (tier 2), was compared with more refined estimates (combining individual food consumption data with actual concentrations measured in food products available on the Belgian market (tier 3)). Estimated daily intakes were compared to the acceptable daily intake (ADI) of the stearoyl-2-lactylates. The results of tier 2 demonstrated that 92% of the children (3–9 years), 53% of the adolescents (10–17 years), 15% of the adults (18–64 years) and 26% of the elderly (64–98 years) had a potential intake higher than the ADI. When replacing the MPL with maximum analysed concentration levels in foods, daily intake estimates decreased dramatically. The estimated daily intake of the food emulsifiers was below the ADI for all age groups, except for a small percentage of children (1.9%) for which the intake exceeded the ADI. The main contributors to the exposure of E481 and E482 were bread, rolls and fine bakery wares.     

Ganglioside Composition Distinguishes Anaplastic Ganglioglioma Tumor Tissue from Peritumoral Brain Tissue: Complementary Mass Spectrometry and Thin-Layer Chromatography Evidence

Gangliosides serve as antitumor therapy targets and aberrations in their composition strongly correlate with tumor growth and invasiveness. Anaplastic ganglioglioma is a rare, poorly characterized, malignant neuronal–glial tumor type. We present the first comparative characterization of ganglioside composition in anaplastic ganglioglioma vs. peritumoral and healthy brain tissues by combining mass spectrometry and thin-layer chromatography. Anaplastic ganglioglioma ganglioside composition was highly distinguishable from both peritumoral and healthy tissue despite having five to six times lower total content. Ten out of twelve MS-identified ganglioside classes, defined by unique glycan residues, were represented by a large number and considerable abundance of individual species with different fatty acid residues (C16–C24) in ceramide portions. The major structurally identified class was tumor-associated GD3 (>50%) with 11 species; GD3 (d18:1/24:0) being the most abundant. The dominant sphingoid base residue in ganglioside ceramides was sphingosine (d18:1), followed by eicosasphingosine (d20:1). The peritumoral tissue ganglioside composition was estimated as normal. Specific ganglioside composition and large variability of ganglioside ceramide structures determined in anaplastic ganglioglioma demonstrate realistic ganglioside expression patterns and correspond to the profile of high-grade malignancy brain tumors.     

Prediction of pressure–viscosity coefficient of lubricating oils based on sound velocity

The pressure–viscosity coefficient is an important parameter in tribology. Experimentally, it is calculated using the high‐pressure viscosity measurement. Also, the adiabatic bulk modulus is calculated using the sound velocity in the lubricating oil. Several lubricating oils are considered on the group basis such as traction oil, mineral oil, polyalphaolefin oil, perfluoropolyether oil and glycerol, depending on their molecular structure. Experimental pressure–viscosity coefficient is compared with the adiabatic bulk modulus. It is found that the pressure–viscosity coefficient increases exponentially with the adiabatic bulk modulus, and the relationship depends on the molecular structure of the lubricating oils. This study proposes two equations to predict the pressure–viscosity coefficient from the adiabatic bulk modulus based on sound velocity, one for the traction oil, and another for the paraffinic mineral oil and the polyalphaolefin oil. Copyright © 2009 John Wiley & Sons, Ltd.     

Setting Up a Numerical Model of a DAF Tank: Turbulence, Geometry, and Bubble Size

This paper discusses the modeling framework and identifies a number of parameters relevant when setting up a computational fluid dynamics simulation of a dissolved air flotation (DAF) tank. The selection of a turbulence model, the choice between performing two-dimensional (2D) or three-dimensional (3D) simulations, the effects of the design of the flow geometry and the influence of the size of the air bubbles are addressed in the paper. The two-phase flow of air and water is solved in the Eulerian-Lagrangian frame of reference. The realizable k-ε model with nonequilibrium wall functions is suggested as a compromise between a need to effectively resolve the flow and the cost of the simulations. There is a discussion on the conditions for which the steady-state simulations are appropriate. We demonstrate that a steady 2D model can simulate a stratified flow pattern. Our results show that 2D models require adjustments in geometry (e.g., substitution of the outlet pipes to an outlet distributed over the total width of the tank) and in the parameters governing the flow in order to account for the true 3D nature of some of the flow patterns. In addition, we show that the bubble size has a larger influence on the flow in the separation zone than in the contact zone.     

Evaluation of machinability and economic performance in cryogenic-assisted hard turning of α-β titanium: a step towards sustainable manufacturing

Abstract

Titanium, a difficult-to-cut material, consumes higher time and cost in removing material by machining to produce parts. Machining of Ti alloys has got serious attention owing to its reactive nature with tool materials at elevated temperature that aggravates tool wear. Reportedly, effective and efficient cooling and lubrication at the tool–work interface can ameliorate the machinability of Ti-alloys. In this perspective, this article interrogates the underlying mechanism of critical responses such as surface roughness, temperature, tool life and machining cost under dry, minimum quantity lubrication (MQL) and cryogenic liquid nitrogen (LN2) modes. The effect of cutting speeds and feed rates on such responses have been considered as a function of cooling strategy to standardize the cooling technique as the best alternative for machining. Cryogenic cooling seems to be preponderant regarding machining cost, temperature, surface roughness and tool life in hard turning of a–b titanium alloy. The feasibility of cryogenic cooling was investigated using the iso-response technique in comparison with dry and MQL-assisted hard turning. Experimental results revealed longer tool life and lower machining cost under cryogenic condition followed by MQL and dry machining. Moreover, cryogenic LN2 has been identified as an appropriate alternative to reduce the temperature and surface roughness. On contrary, dry turning evoked a high-temperature and rapid tool wear. In a nutshell, cryogenic assisted hard turning has acceded as a sustainable strategy from an environmental and economic perspective.     

Characterizing SERCA Function in Murine Skeletal Muscles after 35–37 Days of Spaceflight

It is well established that microgravity exposure causes significant muscle weakness and atrophy via muscle unloading. On Earth, muscle unloading leads to a disproportionate loss in muscle force and size with the loss in muscle force occurring at a faster rate. Although the exact mechanisms are unknown, a role for Ca²⁺ dysregulation has been suggested. The sarco(endo)plasmic reticulum Ca²⁺ ATPase (SERCA) pump actively brings cytosolic Ca²⁺ into the SR, eliciting muscle relaxation and maintaining low intracellular Ca²⁺ ([Ca²⁺]_i). SERCA dysfunction contributes to elevations in [Ca²⁺]_i, leading to cellular damage, and may contribute to the muscle weakness and atrophy observed with spaceflight. Here, we investigated SERCA function, SERCA regulatory protein content, and reactive oxygen/nitrogen species (RONS) protein adduction in murine skeletal muscle after 35–37 days of spaceflight. In male and female soleus muscles, spaceflight led to drastic impairments in Ca²⁺ uptake despite significant increases in SERCA1a protein content. We attribute this impairment to an increase in RONS production and elevated total protein tyrosine (T) nitration and cysteine (S) nitrosylation. Contrarily, in the tibialis anterior (TA), we observed an enhancement in Ca²⁺ uptake, which we attribute to a shift towards a faster muscle fiber type (i.e., increased myosin heavy chain IIb and SERCA1a) without elevated total protein T-nitration and S-nitrosylation. Thus, spaceflight affects SERCA function differently between the soleus and TA.